Veteran actor Sam Neill (Jurassic Park) and starlet Emmanuelle Chriqui (Entourage) have joined the show. The Ordained stars Charlie Cox (Boardwalk Empire) as Tom, the son of a Kennedy-esque family who leaves the priesthood and becomes a lawyer in a bid to prevent his politician sister from being assassinated.

Neill will play Tom’s father, who’s often called “The Governor” (no eye patch, presumably) while Chriqui plays Tom’s literal girl next door.

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Chriqui is not just the first celebrity face of Charles David, but she’ll also be designing a capsule collection for fall. To kick off the collaboration, she shot her first round of ads in L.A. with photographer Patrick Hoelck, styled by Britt Bardo — and she shared some behind-the-scenes photos from the shoot with PEOPLE. Read on to see the gorgeous pics and hear Chriqui’s take on the shoot (spoiler alert: they “laughed a lot” on set!)

“The shoot was amazing. It all came together beautifully,” Chriqui says of the day-long shoot in October. “Patrick is such a fun spirit. It didn’t feel like a long day at all!”

Of the many gorgeous shoes Chriqui modeled, her favorite were the white “Sway” style, pictured above. They’re “so amazing to throw on with a pair of jeans,” she says. “If I could own every color of the ‘Sway’ pump, I would. They’re super sexy!”

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“There Will Be Blood” – Lorelei Martins returns, determined to find out if Red John had a role in her sister’s death, and Jane is forced to confess to Lisbon his part in Lorelei’s prison escape, on THE MENTALIST, Sunday, March 10 (10:00-11:00 PM, ET/PT) on the CBS Television Network. Emmanuelle Chriqui returns as Lorelei Martins.